 |
| © Eugene Brennan |
What Are Plastics?
"Plastic"
is a term applied to any material that can be moulded or bent into
shape; for instance, soft toffee, modelling clay, or red-hot iron is
plastic because it can be reshaped. In general though, when we speak of
plastic, we mean polymers or synthetic materials made from
petrochemicals.
There are at least 10 different types of plastics
used in the home, the type used depending on the application. Many of
these plastics can be recycled and are marked with a symbol and numeric
code indicating the plastic type.
Types of Plastic Used Around the Home
There are lots of different types of plastics used in and about the home. The most common ones are:
- Polyethylene (Polythene)
- Poly Vinyl Chloride (PVC), also known as vinyl
- Polypropylene
- Polystyrene
- Polytetrafluoroethylene (Teflon)
- Nylon
- Polyesters, polyethylene terephthalate (PET) being the most common
- Acrylic
- Polycarbonate
- Polyurethane
Note: These numbers are not the plastic ID codes. See the information about each plastic below for codes.
What Is Plastic Used For?
Well
virtually everything! From the '60s onwards, plastic began to replace
or supplement many items which were traditionally made from materials
such as metal, wood, glass, stone, ceramic and natural textiles. Some
examples:
- Textiles: Cotton, wool, silk,
linen and hemp were the original textiles used from ancient times. We
now have acrylic, polyester and nylon.
- Footwear: Shoes originally had leather uppers and soles. PVC is now used for trainers, and soles are made from PVC or polyurethane foam.
- Windows and doors: Originally made from timber, they are now also made from PVC.
- Food storage, eating and drinking utensils and bottles: They were originally ceramic, glass or metal but are now also made from polyester, polypropylene and polyethylene (Polythene.)
- Electrical insulation: Originally rubber, now also PVC.
- Furniture: Plastics such as polystyrene are used
for stackable, hard seating. Padded seating coverings are often made
from PVC or "vinyl," and soft, flexible, polyurethane foam forms the
internal padding.
- Car and machine parts: Many parts in cars were made
from metals such as steel, brass, aluminium alloy and rubber. These are
now often replaced by plastics such as PVC, nylon, ABS and polystyrene.
- Casings of electronic/electrical devices and appliances: Originally made from wood, metal or Bakelite, they are now generally made from polystyrene, polypropylene or ABS.
- Fixtures and fittings in homes: Lighting, electrical fittings and conduit and bathroom fittings.
- Plumbing: PVC, PEX (cross-linked high-density
polyethylene), polybutylene and CPVC are extensively used for domestic
plumbing, drainage pipes, water distribution mains to homes, gas
distribution and protective conduit for underground electrical cables.
Why Is Plastic Used So Much?
- It's cheap and made from a relatively inexpensive raw material.
- It's relatively strong and can be used for many applications.
- Many plastics are inert, so they can be used in contact with
solvents, acids and alkalis, water and other chemicals without suffering
any ill effects.
- Unlike organic materials such as wood and natural textiles, plastic
doesn't decay when exposed to wet or damp conditions for long periods.
- Thermoplastics can be moulded into lots of different shapes using an
industrial process called injection moulding (basically forcing soft
plastic into a mould under high pressure). So no machining is necessary,
as is the case with metals. Plastics can also easily be 3D printed.
- Plastics can be easily coloured.
- Nylon, a tough and durable type of plastic, can be used for moving
parts in machinery without the requirement of lubrication (it has a
relatively low coefficient of friction like Teflon.)
- Plastic is a non conductor of electricity, so it can be used as an insulator in electrical appliances.
- Many plastics can be easily recycled by being melted down or shredded to make new products.
- As a synthetic fibre, it can be more durable than natural fibres when made into textiles.
- Many plastics are good thermal insulators, so they are used as handles on kitchen utensils, tools, saucepan lids etc.
What Are the Disadvantages of Plastic?
- Unlike
scrap metals, for instance—which are more valuable—plastic is such a
ubiquitous and cheap material that there has been very little incentive
to recycle it until recent decades. So it ends up in landfills and as
litter.
- For some applications, plastics cannot be used because they lack the
strength of metals. Composite materials such as carbon fibre (a fibre reinforced polymer) will eventually become more widely used.
- While plastic parts are often used in machines and tools, they
aren't as tough or durable as metal, so plastic parts can wear or break
more easily.
- Ultra Violet (UV) exposure from sunlight can cause plastics to crack
and degrade over time unless special additives are added to the
material during manufacture.
- There are concerns about carcinogens used as fillers or trapped
monomers leaching out of plastics used in food storage containers and
drinking vessels.
- It can't be used for applications where it is exposed to very high temperatures.
- Microbeads less than 1mm diameter used in personal care products as
an abrasive pose an environmental hazard and may harm aquatic animals.
What Are the Two Main Categories of Plastics?
Plastics can be broadly divided into thermoplastic and thermosetting types.
Thermosets
are heated during manufacture, and a non-reversible chemical reaction
takes place. Once they have cooled and set, they stay solid and can't be
re-heated and re-moulded, e.g. for recycling. Examples are Bakelite,
urea formaldehyde and vulcanisation of rubber.
Thermoplastics can
be reheated repeatedly without undergoing any chemical change. This
allows them to be reshaped or recycled into new materials. Examples are
PVC, polyethylene and polypropylene.
What Is Plastic Made Of?
There are several stages in the manufacture of plastic, but it all starts
with crude oil and natural gas. There are three main stages:
- Stage 1: Crude oil (petroleum) and natural gas are extracted from ground.
- Stage 2: Intermediate products known as petrochemicals are made from crude oil and natural gas.
- Stage 3: Polymerisation and other chemical processes are used to produce plastics from petrochemicals.
Stage 1: Crude Oil and Natural Gas, the Raw Materials for Plastic
The raw material for most plastics is crude oil, also known as petroleum.
This is a thick black, brown, yellowish or greenish liquid extracted
from the ground using oil wells on land or at sea. Crude oil was formed
when creatures and plants such as zooplankton and algae died and settled
to the bottom of the ocean. Over millions of years, sand, shells and
other stuff collected on top of them. As a result of heat and pressure,
this organic material was transformed into oil.
Crude oil is a complex mix or soup of lots of chemicals and must be refined.
Oil refineries are large industrial complexes which process thousands
of barrels of oil daily. In a refinery the oil is cleaned of
contaminates such as salt water. Several processes are then used to
break the oil up into its constituent components, typical of which is
fractional distillation. In this process, oil is heated, and various
compounds boil off at different temperatures and can be separated. This
results in distillates such as petrol (gasoline), kerosene, lubricating oil, wax
and bitumen. Petrochemicals such as benzene, toulene and xylene or BTX
are also produced here.
Natural gas is also used as a raw
material. This is processed at a natural gas processing plant into a
variety of different types of gases.
 |
| Diagram depicting the how petrochemical plant feedstocks are obtained. CC by SA 3.0 Unported via Wikimedia Commons |
Petrochemicals are the intermediate chemicals in the production of plastics. Typical
petrochemicals are ethylene, propylene, benzene, butadeine, toulene, and
xylene. Petrochemicals are produced in petroleum refineries, natural
gas processing plants and by a process known as cracking.
Stage 3: Polymerisation
In
this process, the petrochemical monomer raw product is converted into a
long chain polymer or plastic. A typical petrochemical is ethylene gas
with the formula C2H4. In the polymerisation
process, an activator known as a catalyst speeds up the chemical
reaction. Lots of ethylene molecules join together into chains to form a
polymer.
 |
| Polymerisation of ethylene to form polyethylene. © Eugene Brennan |
How to Identify Plastic Type
Most
plastic products or their component parts are marked with a resin identification code (RIC) symbol, also known as a plastic
identification code (PIC) specifying the type. This is also sometimes called a recycling code, however this is technically incorrect as not all these plastics are recyclable. This allows ease of
identification for recycling purposes.
 |
| Plastic resin identification code (RIC) embossed onto the underside of a medicine bottle. © Eugene Brennan |
 |
| Resin Identification Code (RIC) for polyester. © Eugene Brennan |
Polyester
There
are many polyesters, but the most common type encountered in the home
is PETE or Polyethylene terephthalate. PETE is spun into a synthetic
fibre which is used to produce textiles. Polyester fibre is also mixed
with natural fibres such as cotton to improve durability.
Uses
- Shirts, trousers, coats and other clothing, sometimes under the brand name "Terylene"
- Bed sheets
- Plastic bottles
- Tarpaulins
- Insulating tapes
- Upholstery
- Insulation in clothing and as padding in duvets, pillows etc
Products Made From PET
 |
| © Eugene Brennan |
 |
| Hi-vis vest. © Eugene Brennan |
 |
| Plastic bottles. © Eugene Brennan |
 |
| Resin Identification Code (RIC) for polyethylene. © Eugene Brennan |
Polyethylene
High
density polyethylene (also known as polythene), has a high strength to weight ratio and also a
high resistance to solvents, acids, and other chemicals.
Uses
- Plastic bags
- Storage containers for food and other products
- Beverage bottles
- Toiletry bottles
- Fuel tanks on vehicles and garden/yard power equipment
- Containers for household cleaning chemicals
- Petrol (gasoline) storage containers
- Storage containers for motor oil
- Blow moulded cases for tools
Products Made From HDPE
 |
| Plastic power tool case. © Eugene Brennan |
 |
| Plastic bottles. © Eugene Brennan |
 |
| Safety helmet. © Eugene Brennan |
 |
| Resin Identification Code (RIC) for PVC. © Eugene Brennan |
Poly Vinyl Chloride (PVC)
Poly
Vinyl Chloride is more commonly known by the abbreviation PVC or
"vinyl." It comes in two forms rigid or flexible. The rigid form is used
for structural work such as door and window frames and the frame
members of plastic greenhouses. The flexible form is widely used as
electrical insulation, upholstery coverings, and inflatable products.
Uses
- Doors, windows, and greenhouse frames
- Upholstery covering, chair seat coverings
- Beach balls, footballs and other inflatable products
- Fascia and soffit
- Downpipes and gutters
- Waste and water pipe
- Insulation for electrical wire
- Electrical conduit
- "Vinyl" records
Products Made From PVC
 |
| Gutters and downpipe. © Eugene Brennan |
 |
| Waste pipe. © Eugene Brennan |
 |
| PVC window. © Eugene Brennan |
 |
| Fascia and soffit. © Eugene Brennan |
 |
| Electrical conduit and saddle clip. © Eugene Brennan |
 |
| Insulation on electric cable. © Eugene Brennan |
 |
| Resin Identification Code (RIC) for low-density polyethylene. © Eugene Brennan |
Low Density Polyethylene (LDPE)
Low Density Polyethylene is a soft flexible plastic widely used for making
clear plastic bags and sheeting. It has a higher resilience than HDPE,
which basically means that it can be stretched or deformed more without
cracking or ripping. You can tell the difference between an LDPE and
HDPE bag by scrunching them up. HDPE bags make lots of crackly noise. It
is also ideal for snap-on lids, as it can deform and seal around the
rim of the container.
Uses
- Plastic bags
- Clear, flexible plastic sheeting, e.g., for polytunnels
- Soft, flexible snap on lids
- Shrink wrap (cling film)
- Waterproof linings of cardboard juice and milk cartons
Products Made From LDPE
 |
| Soft plastic bag. © Eugene Brennan |
 |
| Resin Identification Code (RIC) for polypropylene. © Eugene Brennan |
Polypropylene
Polypropylene
is a tough, flexible plastic and used for applications which require
these properties. It also resistant to fatigue, which means that it can
be repeatedly deformed or strained without cracking. PP also has good
resistance to acids and solvents. Polypropylene is able to withstand
higher temperatures than HDPE, and so is used for applications where a
product must be sterilised or heated, e,g. kettles and dishwasher proof
kitchenware. It is also used for containers which contain dairy products
such as butter, as it can withstand the heat given off by products
during industrial filling processes.
A disadvantage of PP is that
it degrades when exposed to heat and UV present in sunlight, so
additives must be used if products are required to be long lasting in
sunshine.
Uses
- Beverage bottles
- Dish washer proof plates and food storage containers
- Living hinges on lids
- Food storage containers
- Dairy product containers
- Toiletry bottles
- Ropes
- Coal sacks
- Ratchet straps (tie-down straps for holding loads during transport)
Products Made From Polypropylene
 |
| Lids on jars. © Eugene Brennan |
 |
| Butter spread container. © Eugene Brennan |
 |
| Flower pot. © Eugene Brennan |
 |
| Rope. © Eugene Brennan |
 |
| Ratchet strap. © Eugene Brennan |
 |
| Coal sack. © Eugene Brennan |
 |
| Pringles lid. © Eugene Brennan |
 |
| Resin Identification Code (RIC) for polystyrene. © Eugene Brennan |
Polystyrene
Polystyrene
has two main advantages. It is a stiff and rigid polymer, and unlike
other plastics which are translucent or opaque, polystyrene can be made
clear. So it is ideal for applications which require these
characteristics such as CD and display cases.
Uses
- CD cases and display boxes
- Casings for kitchen appliances, TVs and Radios, torches and other electrical gadgets
- Seed trays
- Blister packing
- Disposable cutlery
- Disposable ballpoint pens
- Expanded polystyrene (Styrofoam) is used as insulation, as a packing material and for disposable cups.
Products Made From Polystyrene
 |
| Measuring jug. © Eugene Brennan |
 |
| CD case. © Eugene Brennan |
 |
| Seedling tray. © Eugene Brennan |
 |
| Ballpoint pen casing. © Eugene Brennan |
 |
| Resin Identification Code (RIC) for other plastics. © Eugene Brennan |
Other Plastics Used in the Home
Several polymers which don't have their own specific recycling number are
classed under category seven as "other plastics." Not all of these are
recyclable.
- Nylon - Tough and durable and used for ladies tights, sports clothing and moving parts in machines.
- Polycarbonate - This is tough and durable and can
be bent and deformed to a large extent without cracking. It is used for
making sunglasses, safety glasses, CDs and as synthetic "glass" in
greenhouses.
- Acrylonitrile butadiene styrene (ABS) - Another
tough plastic with high impact resistance. It is used for making Lego
bricks, carrying cases, electrical boxes and computer monitor and
printer cases.
- Urea formaldehyde - Commonly used for sockets, plugs, switches and other electrical fittings.
- Polyurethane - Used in foam form as a padding in
cushions and upholstery, air filters on lawn mower engines and as
packing. Some air and fuel lines are made from this material. Hard foam
soles on footwear are also polyurethane-based.
- Polytetrafluoroethylene (PTFE) - This plastic has a
very low friction coefficient, i.e., it is "slippy." It is known by the
brand name Teflon as the non-stick coating on cooking utensils. It is
also used in tape form for sealing the threads on plumbing joints.
- Polymethyl methacrylate (PMMA) or Acrylic
- Used as a synthetic fibre in sweaters and as clear sheeting or pipe
under the trade names "Perspex," "Plexiglas," "Acrylite," and "Lucite."
- Nitrile rubber - One of the many types of synthetic
rubbers. These are used for a variety of products, including gloves,
o-rings, sealants, fuel lines and water hoses in vehicles, wellingtons
and anything which requires a flexible, waterproof material.
Products Made From Other Plastics
 |
| Nylon strimmer (string trimmer) line. © Eugene Brennan |
 |
| Nylon tights. © Eugene Brennan |
 |
| Nylon gears in a clock mechanism. © Eugene Brennan |
 |
| Urea-formaldehyde electrical fittings. © Eugene Brennan |
 |
| Polycarbonate safety glasses. © Eugene Brennan |
 |
| Polycarbonate CD. © Eugene Brennan |
 |
| PTFE plumber's tape. © Eugene Brennan |
 |
| Polyurethane foam air filter. © Eugene Brennan |
 |
| Nitrile rubber O-ring. © Eugene Brennan |
Older Plastics Used in the Home:
- Bakelite -
This is a thermosetting plastic used in the past for electrical
fittings, electrical insulation, door knobs and saucepan handles.
Because it is a thermoset, it doesn't melt or deform when subjected to
high temperatures.
- Celluloid - Used for making dolls, musical instruments, pens, table tennis balls, cutlery handles and as a veneer for clocks and furniture
 |
| Bakelite plug. © Eugene Brennan |
 |
| Bakelite door knob. © Eugene Brennan |
 |
| Celluloid knife handle. © Eugene Brennan |
Recyclable Plastics
Not all plastics are recyclable, but it depends on region and country. Soft
plastic made from low and high density polyethylene, expanded
polystyrene packing, and hard polystyrene casings (such as plastic bags
and film) are generally not accepted by waste collection service
providers. Expanded polystyrene needs to be compacted, and the cost of
building large compactors is high.
PET, HDPE, and PP (used in bottles, lids, food trays and containers) are generally recyclable.
What Products Are Made From Recycled Plastic?
According
to the World Wildlife Foundation (WWF), eight million tons of plastic
globally is dumped into our oceans. There are limitations on what can be
made from recycled plastic, but typical products are:
- trash bags
- washing machine outer tubs
- garden furniture
- planters
- mats and rugs
- footwear
Plastics in the Ocean: What Are Microplastics?
Tiny
microbeads less than 1mm diameter made from polyethylene, polypropylene
and polystyrene are used as an abrasive ingredient in personal care
products such as skin exfoliating creams and toothpaste. These materials
end up in waste water and pass through sewage treatment plants
unhindered, and then get carried via rivers to our oceans. These pose an
environmental hazard and may harm aquatic animals.
Plastic items
in our home and from land based industry and fishing activity also
degrade over time, and the tiny fragments eventually end up in the
ocean. Larger items such as plastic bottles, floats from fishing nets,
items lost or disposed of overboard from ships also pollute the seas.
Let Me Know Your Thoughts!
Was the information in this article useful and instructive? If there you
have any suggestions for improvement or any questions, please provide
some feedback below. Thanks!
Disclaimer
This article is accurate and true
to the best of the author’s knowledge. Content is for informational or
entertainment purposes only and does not substitute for personal counsel
or professional advice in business, financial, legal, or technical
matters.
© 2014 Eugene Brennan