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When
 you touch a spoon or walk on ceramic tiles, they feel cold, yet 
expanded polystyrene packing feels warm as though it’s generating heat.
It’s because of the differing thermal conductivities of the two materials. Heat capacity also has a part to play.
So what are these physical properties?
A
 piece of metal, tile and polystyrene left in a room for a sufficiently 
long period will all have stabilised at a temperature equal to the 
ambient temperature in the room. However metal and to a lesser extent 
ceramic have a much higher thermal conductivity than expanded 
polystyrene. Thermal conductivity is a measure of the rate at which a 
material can transfer heat energy. 
 
Difference between heat and temperature
 
• Heat
 is the amount of thermal energy an object has. It's measured in joules.
 2 kilos of a substance has double the thermal energy of 1 kilo of that 
substance at the same temperature. 
 
• Temperature
 is a measure of the amount of activity of the atoms in a substance. 
It's the movement of atoms: vibration, spin and translation (movement 
from one place to another) that gives rise to the temperature of an 
object. The greater the movement, the higher the temperature. If you've 
ever been splashed by grease when cooking or hit by a spark from a fire,
 they were at a temperature of several hundred degrees. However because 
the splash or spark were small, they didn't have a lot of heat energy 
and cooled down quickly, compared to having a larger amount of the 
material making contact with the skin. 
 
Back to the spoons
 
The
 temperature of the surface of your finger is likely to be over 30 
degrees Celsius, however the temperature in a room would be typically 10
 degrees or more less than this. Heat always flows from a region of high
 temperature to one of lower temperature. When you touch a spoon, heat 
flows from your warm finger to the spoon and the cooling effect is 
detected by temperature sensors in your skin. The cooling effect is 
quicker for materials such as metal with a high thermal conductivity 
because they transfer heat energy faster. The scenario is a little 
different when touching expanded polystyrene. Because a room will be 
colder than your finger, your finger is constantly cooling down as air 
moves around it. However if the room temperature is constant, 
equilibrium is eventually reached and the surface of your finger will 
eventually settle at a temperature cooler than that under the surface of
 the skin, assuming your body continues to provide heat.  When you touch
 a piece of polystyrene, because it has a low thermal conductivity, heat
 flows into it at a very low rate. However if it covers the pad of your 
finger, the heat loss from your finger to the surrounding air will be 
reduced. That reduction is likely to be greater than the heat transfer 
to the polystyrene, so your finger will tend to warm up. So it’s not the
 polystyrene that’s generating heat, making it appear warm, but your 
finger heating up because it no longer cools as it loses heat to the 
surrounding air.
Thermal conductivity is measured in watts per meter-kelvin ( W/(m K) )
 
Joules and Kelvin
 
Temperature is measured in degree Celsius. The zero point on the scale is the freezing point of water and 100 degrees is the temperature water boils at. For scientific purposes, the Kelvin scale is used, and the only difference between it and the Celsius scale is that the zero point is shifted to absolute zero. Absolute zero is  when all movement of atoms ceases. It has never been reached, but we have cooled substances to within tiny fractions of a degree above absolute zero. The divisions on the Celsius and Kelvin scales are the same, so a temperature change of 1 °C = 1 K. (Note that the  ° symbol is not used with the unit’s symbol “K”.)
 
Why does it feel colder on damp days?
 
Higher
 thermal conductivity of water versus air explains why damp days feel 
colder than when air humidity is lower, even though the air temperature 
is the same. Winter temperature in continental climates is often much 
less than in Ireland, but because of the dry air, it never feels as 
cold. 
 
Heat capacity
 
This
 is another property of matter that can influence how we perceive 
cooling. It’s defined as the amount of heat required to change the 
temperature of a substance by 1 K. Water compared to other liquids has a
 huge heat capacity and requires lots of heat energy to raise its 
temperature. The specific heat capacity of a substance is the amount of 
heat energy required to raise 1 kg of that substance by 1 K. The SHC of 
water is approximately 4200 J/(kg K). (Expressed as 4200 joules per 
kilogram per degree kelvin.) 
If
 you dip your finger into water, since water has a high SHC, it 
continues to drain heat energy, lowering the finger's temperature. A 
liquid with a lower SHC such as olive oil would rise in temperature 
faster, and if there was no mixing of the liquid, this would reduce the 
thermal gradient, slowing heat loss. So olive oil wouldn't feel as cold 
if you put your finger in it.
 
Resources
Specific heat capacities if different materials: